Mayr's Database of Reactivity Parameters

Aliphatic amines

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Aliphatic amines

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
n-propylamine (in MeCN)
*
 MeCN

N  Param.: 15.11

sN Param.: 0.63		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
n-butylamine (in MeCN)
*
 MeCN

N  Param.: 15.27

sN Param.: 0.63		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
dipropylamine (in MeCN)
*
 MeCN

N  Param.: 14.51

sN Param.: 0.80		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
diethylamine (in MeCN)
*
 MeCN

N  Param.: 15.10

sN Param.: 0.73		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
morpholine (in MeCN)
*
 MeCN

N  Param.: 15.65

sN Param.: 0.74		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
piperidine (in MeCN)
*
 MeCN

N  Param.: 17.35

sN Param.: 0.68		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
di(methoxyethyl)amine (in MeCN)
*
 MeCN

N  Param.: 13.24

sN Param.: 0.93		 *** Eur. J. Org. Chem. 2009, , 6379-6385
10.1002/ejoc.200900925
triethylamine (in MeCN)
*
 MeCN

N  Param.: 17.10

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
triethylamine (in CH2Cl2)
*
 dichloromethane

N  Param.: 17.30

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 20.59

sN Param.: 0.52		 *** J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707