Mayr's Database of Reactivity Parameters

Azoles and Azole Anions

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Azoles and Azole Anions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-methyl-benzotriazole (in MeCN)
*
 MeCN

N  Param.: 7.77

sN Param.: 0.76		 * Org. Biomol. Chem. 2010, 8, 1929-1935
10.1039/c000965b
imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.09

sN Param.: 0.51		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.03

sN Param.: 0.50		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.29

sN Param.: 0.51		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2,4-dimethyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 20.69

sN Param.: 0.60		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-nitro-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 14.81

sN Param.: 0.71		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-formyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 16.06

sN Param.: 0.68		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-formyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 16.40

sN Param.: 0.67		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
benzimidazole anion (in DMSO)
*
 DMSO

N  Param.: 19.13

sN Param.: 0.55		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
benzotriazole anion (in DMSO)
*
 DMSO

N  Param.: 16.29

sN Param.: 0.65		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411