Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
H2O (in water)
H2O *
 water

N  Param.: 5.20

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
OH- (in 50/50 water/MeCN)
HO *
 water-MeCN mix

N  Param.: 10.19

sN Param.: 0.62		 *** J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
OH- (in water)
HO *
 water

N  Param.: 10.47

sN Param.: 0.61		 *** J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
2,2,2-trifluoroethanolate (in water)
C2H2F3O *
 water

N  Param.: 12.66

sN Param.: 0.59		 *** J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
HOO- (in water)
HO2 *
 water

N  Param.: 15.40

sN Param.: 0.55		 *** J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
10% water/90% acetone (v/v)
H2O *
 water-acetone mix

N  Param.: 5.70

sN Param.: 0.85		 *** Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
20% water/80% acetone (v/v)
H2O *
 water-acetone mix

N  Param.: 5.77

sN Param.: 0.87		 *** Angew. Chem. Int. Ed. 2004, 43, 2302-2305
10.1002/anie.200353468
91% water/9% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.16

sN Param.: 0.91		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
80% water/20% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.04

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
67% water/33% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.05

sN Param.: 0.90		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z