O-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
10% water/90% HFIP (w/w)	water-HFIP mix	N Param.: 0.96 s_N Param.: 0.93	J. Phys. Org. Chem. 2013, 26, 59-63 10.1002/poc.3064
10% water/90% MeCN (v/v)	water-MeCN mix	N Param.: 4.56 s_N Param.: 0.94	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
10% water/90%EtOH (v/v)	water-EtOH mix	N Param.: 7.03 s_N Param.: 0.86	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
10% water/90%TFE (v/v)	water-TFE mix	N Param.: 2.93 s_N Param.: 0.88	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
2% water/98% HFIP (w/w)	water-HFIP mix	N Param.: -1.62 s_N Param.: 1.10	J. Phys. Org. Chem. 2013, 26, 59-63 10.1002/poc.3064
2,2,2-trifluoroethanolate (in water)	water	N Param.: 12.66 s_N Param.: 0.59	J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y
2-phenylperoxyacetate (in H2O)	water	N Param.: 15.63 s_N Param.: 0.56	Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086
20% ethanol/80% MeCN (v/v)	EtOH-MeCN mix	N Param.: 5.77 s_N Param.: 0.92	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
20% methanol/80% MeCN (v/v)	MeOH-MeCN mix	N Param.: 6.04 s_N Param.: 0.94	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
20% water/80% acetone (v/v)	water-acetone mix	N Param.: 5.77 s_N Param.: 0.87	Angew. Chem. Int. Ed. 2004, 43, 2302-2305 10.1002/anie.200353468