Mayr's Database of Reactivity Parameters

O-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
3-chloroperoxybenzoate (in H2O)
C7H4ClO3 *
 water

N  Param.: 18.19

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-fluoroperoxybenzoate (in H2O)
C7H4FO3 *
 water

N  Param.: 17.99

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-nitroperoxybenzoate (in H2O)
C7H4NO5 *
 water

N  Param.: 17.43

sN Param.: 0.50		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-methoxyperoxybenzoate (in H2O)
C8H7O4 *
 water

N  Param.: 17.84

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3-chloro-4-methoxyperoxybenzoate (in H2O)
C8H6ClO4 *
 water

N  Param.: 18.56

sN Param.: 0.48		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
peroxybenzoate (in H2O)
C7H5O3 *
 water

N  Param.: 18.57

sN Param.: 0.43		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
hypochlorite (in water)
ClO *
 water

N  Param.: 14.50

sN Param.: 0.58		 *** Org. Lett. 2018, 20, 2816-2820
10.1021/acs.orglett.[...]
hypobromite (in water)
BrO *
 water

N  Param.: 16.69

sN Param.: 0.46		 *** Org. Lett. 2018, 20, 2816-2820
10.1021/acs.orglett.[...]
bromite (in water)
BrO2 *
 water

N  Param.: 12.75

sN Param.: 0.59		 *** Org. Lett. 2018, 20, 2816-2820
10.1021/acs.orglett.[...]
peroxomonosulfate (in water)
O5S *
 water

N  Param.: 14.41

sN Param.: 0.60		 *** Org. Lett. 2018, 20, 2816-2820
10.1021/acs.orglett.[...]