Mayr's Database of Reactivity Parameters

Alcohols and aqueous solvents

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Alcohols and aqueous solvents

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1% water/99% HFIP (w/w)
*
 water-HFIP mix

N  Param.: -1.93

sN Param.: 1.09		 *** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
methanol (in MeCN)
*
 MeCN

N  Param.: 6.86

sN Param.: 0.73		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
ethanol (in MeCN)
*
 MeCN

N  Param.: 7.13

sN Param.: 0.71		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
isopropanol (in MeCN)
*
 MeCN

N  Param.: 6.82

sN Param.: 0.70		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
tert-butanol (in MeCN)
*
 MeCN

N  Param.: 5.35

sN Param.: 0.72		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
water (in MeCN)
*
 MeCN

N  Param.: 5.79

sN Param.: 0.72		 *** Bull. Chem. Soc. Jpn. 2018, 91, 523-530
10.1246/bcsj.20170360
50% water/50% MeCN (v/v)
H2O *
 water-MeCN mix

N  Param.: 5.05

sN Param.: 0.89		 *** J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z