Mayr's Database of Reactivity Parameters

Allyl Element Compounds

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Allyl Element Compounds

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
allyltrimethylsilane
C6H14Si *
 dichloromethane

N  Param.: 1.68

sN Param.: 1.00		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
allyltriphenylstannane
C21H20Sn *
 dichloromethane

N  Param.: 3.09

sN Param.: 0.90		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)trimethylsilane
C7H16Si *
 dichloromethane

N  Param.: 4.41

sN Param.: 0.96		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allyltributylstannane
C15H32Sn *
 dichloromethane

N  Param.: 5.46

sN Param.: 0.89		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)tributylstannane
C16H34Sn *
 dichloromethane

N  Param.: 7.48

sN Param.: 0.89		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allyltriphenylsilane
C21H20Si *
 dichloromethane

N  Param.: -0.13

sN Param.: 1.21		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)triphenylsilane
C22H22Si *
 dichloromethane

N  Param.: 4.17

sN Param.: 0.79		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allylchlorodimethylsilane
C5H11ClSi *
 dichloromethane

N  Param.: -0.57

sN Param.: 1.06		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
trimethyl(prenyl)silane
C8H18Si *
 dichloromethane

N  Param.: 0.90

sN Param.: 1.17		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)triphenylgermane
C22H22Ge *
 dichloromethane

N  Param.: 4.67

sN Param.: 0.81		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y