S- and Se-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
dimethylselenide (in CH2Cl2)	dichloromethane	N Param.: 12.60 s_N Param.: 0.72	Chem. Eur. J. 2021, 21, 11367-11376 10.1002/chem.202100977
dibutylsulfide (in CH2Cl2)	dichloromethane	N Param.: 11.86 s_N Param.: 0.74	Chem. Eur. J. 2021, 21, 11367-11376 10.1002/chem.202100977
4-nitrothiophenolate (in DMSO)	DMSO	N Param.: 18.92 s_N Param.: 0.87	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-methylthiophenolate (in DMSO)	DMSO	N Param.: 24.35 s_N Param.: 0.69	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-methylpiperazin-1-yl dithiocarbamate (in MeCN)	MeCN	N Param.: 23.61 s_N Param.: 0.57	Org. Biomol. Chem. 2011, 9, 8046-8050 10.1039/c1ob06245j
4-methoxythiophenolate (in DMSO)	DMSO	N Param.: 24.97 s_N Param.: 0.68	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-bromothiophenolate (in DMSO)	DMSO	N Param.: 22.80 s_N Param.: 0.78	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
4-(trifluoromethyl)thiophenolate (in DMSO)	DMSO	N Param.: 21.30 s_N Param.: 0.86	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
3-chlorothiophenolate (in DMSO)	DMSO	N Param.: 22.50 s_N Param.: 0.78	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
3-(trifluoromethyl)thiophenolate (in DMSO)	DMSO	N Param.: 21.75 s_N Param.: 0.86	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
3,5-bis(trifluoromethyl)thiophenolate (in DMSO)	DMSO	N Param.: 19.71 s_N Param.: 0.86	J. Org. Chem. 2021, 86, 5965-5972 10.1021/acs.joc.1c00025
2-sulfidoacetate (in water)	water	N Param.: 22.62 s_N Param.: 0.43	J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y
cysteine (dianionic, in water)	water	N Param.: 23.43 s_N Param.: 0.42	Org. Biomol. Chem. 2007, 5, 3814-3820 10.1039/b713778h