Mayr's Database of Reactivity Parameters

S- and Se-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles
1 | 2 « Back Found 33 molecules, displaying page 1 of 2 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
dimethylsulfide (in CH2Cl2)
C2H6S*
 dichloromethane

N  Param.: 12.32

sN Param.: 0.72		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dimethylselenide (in CH2Cl2)
C2H6Se*
 dichloromethane

N  Param.: 12.60

sN Param.: 0.72		-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dibutylsulfide (in CH2Cl2)
C8H18S*
 dichloromethane

N  Param.: 11.86

sN Param.: 0.74		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiophene (in CH2Cl2)
C4H8S*
 dichloromethane

N  Param.: 13.10

sN Param.: 0.72		-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiopyran (in CH2Cl2)
C5H10S*
 dichloromethane

N  Param.: 11.94

sN Param.: 0.75		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
phenylsulfinate (in DMSO)
*
 DMSO

N  Param.: 19.60

sN Param.: 0.60		***J. Am. Chem. Soc. 2010, 132, 4796-4805
10.1021/ja9102056
4-nitrothiophenolate (in DMSO)
C6H4NO2S-*
 DMSO

N  Param.: 18.92

sN Param.: 0.87		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
3,5-bis(trifluoromethyl)thiophenolate (in DMSO)
C8H3F6S-*
 DMSO

N  Param.: 19.71

sN Param.: 0.86		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
4-(trifluoromethyl)thiophenolate (in DMSO)
C7H4F3S-*
 DMSO

N  Param.: 21.30

sN Param.: 0.86		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
3-(trifluoromethyl)thiophenolate (in DMSO)
C7H4F3S-*
 DMSO

N  Param.: 21.75

sN Param.: 0.86		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
3-chlorothiophenolate (in DMSO)
C6H4ClS-*
 DMSO

N  Param.: 22.50

sN Param.: 0.78		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
4-bromothiophenolate (in DMSO)
C6H4BrS-*
 DMSO

N  Param.: 22.80

sN Param.: 0.78		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
thiophenolate (in DMSO)
C6H5S-*
 DMSO

N  Param.: 23.36

sN Param.: 0.74		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
4-methylthiophenolate (in DMSO)
C7H7S-*
 DMSO

N  Param.: 24.35

sN Param.: 0.69		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
naphthalene-2-thiolate (in DMSO)
C10H7S-*
 DMSO

N  Param.: 22.55

sN Param.: 0.83		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
4-methoxythiophenolate (in DMSO)
C7H7OS-*
 DMSO

N  Param.: 24.97

sN Param.: 0.68		***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
thiocyanate (in MeCN)
CNS*
 MeCN

N  Param.: 17.94

sN Param.: 0.60		***J. Am. Chem. Soc. 2003, 125, 14126-14132
10.1021/ja037317u
phenylsulfinate (in MeCN)
*
 MeCN

N  Param.: 20.11

sN Param.: 0.59		***J. Am. Chem. Soc. 2010, 132, 4796-4805
10.1021/ja9102056
thioacetate (in MeCN)
*
 MeCN

N  Param.: 21.20

sN Param.: 0.63		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j
O-ethyl dithiocarbonate (in MeCN)
*
 MeCN

N  Param.: 19.30

sN Param.: 0.69		***Org. Biomol. Chem. 2011, 9, 8046-8050
10.1039/c1ob06245j