Mayr's Database of Reactivity Parameters

S- and Se-Nucleophiles

1 | 2 | 3 | 4 « Back Found 33 molecules, displaying page 1 of 4 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
dimethylsulfide (in CH2Cl2)
C2H6S*
dichloromethane

N  Param.: 12.32

sN Param.: 0.72
**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dimethylselenide (in CH2Cl2)
C2H6Se*
dichloromethane

N  Param.: 12.60

sN Param.: 0.72
-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dibutylsulfide (in CH2Cl2)
C8H18S*
dichloromethane

N  Param.: 11.86

sN Param.: 0.74
**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiophene (in CH2Cl2)
C4H8S*
dichloromethane

N  Param.: 13.10

sN Param.: 0.72
-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiopyran (in CH2Cl2)
C5H10S*
dichloromethane

N  Param.: 11.94

sN Param.: 0.75
**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
phenylsulfinate (in DMSO)
*
DMSO

N  Param.: 19.60

sN Param.: 0.60
***J. Am. Chem. Soc. 2010, 132, 4796-4805
10.1021/ja9102056
4-nitrothiophenolate (in DMSO)
C6H4NO2S-*
DMSO

N  Param.: 18.92

sN Param.: 0.87
***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
3,5-bis(trifluoromethyl)thiophenolate (in DMSO)
C8H3F6S-*
DMSO

N  Param.: 19.71

sN Param.: 0.86
***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
4-(trifluoromethyl)thiophenolate (in DMSO)
C7H4F3S-*
DMSO

N  Param.: 21.30

sN Param.: 0.86
***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
3-(trifluoromethyl)thiophenolate (in DMSO)
C7H4F3S-*
DMSO

N  Param.: 21.75

sN Param.: 0.86
***J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025