Mayr's Database of Reactivity Parameters

S- and Se-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » S- and Se-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
4-methylthiophenolate (in DMSO)
C7H7S- *
 DMSO

N  Param.: 24.35

sN Param.: 0.69		 *** J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
naphthalene-2-thiolate (in DMSO)
C10H7S- *
 DMSO

N  Param.: 22.55

sN Param.: 0.83		 *** J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025
4-methoxythiophenolate (in DMSO)
C7H7OS- *
 DMSO

N  Param.: 24.97

sN Param.: 0.68		 *** J. Org. Chem. 2021, 86, 5965-5972
10.1021/acs.joc.1c00025