C-Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone		E Param.: -16.38	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone		E Param.: -16.36	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -16.25	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
p-quinone (C-H)		E Param.: -16.19	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
ani(t-Bu)2QM		E Param.: -16.11	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
2,5-dichloroquinone (C-Cl)		E Param.: -16.11	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
(E)-6-(4-(dimethylamino)benzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -16.07	Chem. Eur. J. 2024, , e202403785 10.1002/chem.202403785
(E)-6-((E)-3-phenylallylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -16.00	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
(E)-N-benzylidene-P,P-diphenylphosphinic amide	DMSO	E Param.: -15.89	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
p-nitrophenyl isothiocyanate	DMSO	E Param.: -15.89	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
tol(t-Bu)2QM		E Param.: -15.83	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
(E)-6-(furan-2-ylmethylene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -15.73	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
fumaronitrile	DMSO	E Param.: -15.71	Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779
1-methylsulfanylpropan-2-one (in DMSO)	DMSO	E Param.: -15.60	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
(E)-6-((1-methyl-1H-indol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -15.55	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
1,2-diaza-1,3-diene 1d	DMSO	E Param.: -15.38	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
phenyl isocyanate	MeCN	E Param.: -15.38	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
1,2-diaza-1,3-diene 1f	MeOH	E Param.: -15.30	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1-phenylprop-2-en-1-one (in DMSO)	DMSO	E Param.: -15.25	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
(E)-6-(4-methoxybenzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -15.20	Chem. Eur. J. 2024, , e202403785 10.1002/chem.202403785