C-Electrophiles
For reactivities of structurally related compounds go to:
Electrophiles
Name |
Solvent |
Reactivity Parameters |
Classification |
Reference (title or
year)
|
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
| E Param.: -16.36 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.25 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
p-quinone (C-H) |
| E Param.: -16.19 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b |
ani(t-Bu)2QM |
| E Param.: -16.11 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
2,5-dichloroquinone (C-Cl) |
| E Param.: -16.11 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b |
(E)-N-benzylidene-P,P-diphenylphosphinic amide |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
p-nitrophenyl isothiocyanate |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
tol(t-Bu)2QM |
| E Param.: -15.83 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
fumaronitrile |
DMSO | E Param.: -15.71 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
1-methylsulfanylpropan-2-one (in DMSO) |
DMSO | E Param.: -15.60 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |