Mayr's Database of Reactivity Parameters

Carbocations

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Carbocations

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
indolecarboxylate derived iminium ion
*
 dichloromethane

E Param.: -9.50

 ** Angew. Chem. Int. Ed. 2009, 48, 5034-5037
10.1002/anie.200900933
(fur)(ani)CH+
C16H15O2 *

E Param.: -0.81

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(mfp)PhCH+
C13H10F *

E Param.: 6.23

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(tfm)PhCH+
C14H10F3 *

E Param.: 6.70

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(dfp)PhCH+
C13H9F2 *

E Param.: 6.74

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(mfp)2CH+
C13H9F2 *

E Param.: 6.87

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(dfp)(mfp)CH+
C13H8F3 *

E Param.: 7.52

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(tfm)2CH+
C15H9F6 *

E Param.: 7.96

 ** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(dfp)2CH+
C13H7F4 *

E Param.: 8.02

 * J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(Ftol)2CH+
C15H13F2 *

E Param.: 5.24

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b