Mayr's Database of Reactivity Parameters

Cationic Metal-π-Complexes

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3
*

E Param.: -0.25

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1,3-diphenylpropyn-1-ylium-Cr(CO)3
*

E Param.: 1.07

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)
*

E Param.: -6.19

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1-phenyl-proyn-ylium-Co2(CO)6
*

E Param.: -0.97

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6
*

E Param.: -1.60

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3-phenylpropyn-1-ylium-Co2(CO)6
*

E Param.: -1.58

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
C6H6OMe+-Fe(CO)3
*

E Param.: -8.94

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
C6H7+-Fe(CO)3
*

E Param.: -7.76

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
C7H7+-Fe(CO)3
*

E Param.: -3.49

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
C7H9+-Fe(CO)3
*

E Param.: -9.21

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
dicarbonyl(cyclopentadienyl)propene-iron(II)
*

E Param.: -11.20

***Helv. Chim. Acta 2005, 88, 1754-1768
10.1002/hlca.200590137
fc(ani)CH+
C18H17FeO*

E Param.: -2.90

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
fc(Me)CH+
C12H13Fe*

E Param.: -2.57

*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
fc(Ph)CH+
C17H15Fe*

E Param.: -2.64

*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
fc2CH+
C21H19Fe2*

E Param.: -8.54

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
Pd-allyl cation
*

E Param.: -10.11

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
propyn-1-ylium-Co2(CO)6
*

E Param.: -0.84

***Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)
*

E Param.: -14.21

***Organometallics 2012, 31, 2416-2424
10.1021/om3000357
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)
*

E Param.: -14.46

***Organometallics 2012, 31, 2416-2424
10.1021/om3000357
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)
*

E Param.: -14.14

***Organometallics 2012, 31, 2416-2424
10.1021/om3000357