Mayr's Database of Reactivity Parameters

Acceptor-Substituted Ethylenes

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles
1 | 2 Forward » Found 117 molecules, displaying page 2 of 2 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
dihydro-2H-pyran-2-one
C5H6O2*
 DMSO

E Param.: -21.80

**Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cycloheptenone
C7H10O*
 DMSO

E Param.: -22.00

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
2-methylcyclopentenone
C6H8O*
 DMSO

E Param.: -22.10

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cyclohexenone
C6H8O*
 DMSO

E Param.: -22.10

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
ethyl 2-methylprop-2-enoate (in DMSO)
C6H10O2*
 DMSO

E Param.: -22.77

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
(E)-4-phenylbut-3-en-2-one (in DMSO)
C10H10O*
 DMSO

E Param.: -23.01

***J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
diethyl 4-(dimethylamino)benzylidene malonate
C16H21NO4*

E Param.: -23.10

***Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate
C18H23NO4*

E Param.: -23.40

*Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
N,N-dimethylprop-2-enamide (in DMSO)
C5H9NO*
 DMSO

E Param.: -23.54

***J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
ethyl (E)-but-2-enoate (in DMSO)
C6H10O2*
 DMSO

E Param.: -23.59

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
diethyl 2-((julolidine-9-yl)methylene)malonate
C20H25NO4*

E Param.: -23.80

*Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
ethyl cinnamate (in DMSO)
C11H12O2*
 DMSO

E Param.: -24.52

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
cinnamonitrile (in DMSO)
C9H7N*
 DMSO

E Param.: -24.60

*J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO)
C15H14O2S*
 DMSO

E Param.: -24.69

**J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
2-methylcyclohexenone
C7H10O*
 DMSO

E Param.: -27.50

*Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
3-methylcyclopentenone
C6H8O*
 DMSO

E Param.: -28.90

*Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
3-methylcyclohexenone
C7H10O*
 DMSO

E Param.: -29.60

*Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A