Mayr's Database of Reactivity Parameters

Acceptor-Substituted Ethylenes

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles
1 | 2 | 3 | 4 | 5 | 6 | 7 Found 135 molecules, displaying page 4 of 7 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
ani(Br)2QM
C14H10Br2O2*

E Param.: -8.63

****Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...]
acrylonitrile (in DMSO)
C3H3N*
 DMSO

E Param.: -19.05

***J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
<i>trans-beta</i>-nitrostyrene
*

E Param.: -13.85

***J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u
4-phenylbut-3-yn-2-one
C10H8O*

E Param.: -16.90

-Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803
4-nitro-<i>trans-beta</i>-nitrostyrene
*

E Param.: -12.37

***J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u
4-methyl-<i>trans-beta</i>-nitrostyrene
*

E Param.: -14.23

***J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u
4-methoxy-<i>trans-beta</i>-nitrostyrene
*

E Param.: -14.70

***J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u
4-cyano-<i>trans-beta</i>-nitrostyrene
*

E Param.: -12.61

***J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u
4-bromo-<i>trans-beta</i>-nitrostyrene
*

E Param.: -13.37

***J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u
4-benzylidene-2,6-di-tert-butylcyclohexa-2,5-dien-1-one
C21H26O*

E Param.: -15.58

***Chem. Eur. J. 2025, 31, e202501224
10.1002/chem.202501224
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline
*
 DMSO

E Param.: -16.53

***Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046
3-methylenetetrahydropyran-2-one
C6H8O2*
 DMSO

E Param.: -19.50

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
3-methylenedihydrofuranone
C5H6O2*
 DMSO

E Param.: -19.40

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
3-methylcyclopentenone
C6H8O*
 DMSO

E Param.: -28.90

*Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
3-methylcyclohexenone
C7H10O*
 DMSO

E Param.: -29.60

*Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
2-phenylethene-1-sulfonyl fluoride
C8H7FO2S*
 DMSO

E Param.: -16.63

***Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875
2-methylcyclopentenone
C6H8O*
 DMSO

E Param.: -22.10

***Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
2-methylcyclohexenone
C7H10O*
 DMSO

E Param.: -27.50

*Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium
C19H12F5N2O*
 DMSO

E Param.: -10.09

***Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...]
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium
C22H23N2O*
 DMSO

E Param.: -11.48

***Top. Catal. 2018, 61, 585-590
10.1007/s11244-018-0[...]