Mayr's Database of Reactivity Parameters

Allyl-Si

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
allyltrihexylsilane
C21H44Si *
dichloromethane

N  Param.: 2.11

sN Param.: 0.95
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(Z)-but-2-enyltrimethylsilane
C7H16Si *
dichloromethane

N  Param.: 1.69

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(E)-but-2-enyltrimethylsilane
C7H16Si *
dichloromethane

N  Param.: 1.94

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2,3-dimethylbut-2-enyl)triethylsilane
C12H26Si *
dichloromethane

N  Param.: 3.15

sN Param.: 1.15
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3-(trimethylsilyl)cyclopentene
C8H16Si *
dichloromethane

N  Param.: 1.77

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3-(trihexylsilyl)cyclopentene
C23H46Si *
dichloromethane

N  Param.: 1.98

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2-methylallyl)trichlorosilane
C4H7Cl3Si *
dichloromethane

N  Param.: -0.57

sN Param.: 0.95
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
allyltris(trimethylsilyl)silane
*
dichloromethane

N  Param.: 1.95

sN Param.: 0.98
*** Org. Lett. 2010, 12, 5206-5209
10.1021/ol102220e
(2-methylallyl)tris(trimethylsilyl)silane
*
dichloromethane

N  Param.: 4.63

sN Param.: 0.87
*** Org. Lett. 2010, 12, 5206-5209
10.1021/ol102220e
2-phenyl-allyltrimethylsilane
C12H18Si *
dichloromethane

N  Param.: 5.38

sN Param.: 0.89
*** Chem. Eur. J. 2014, 20, 1103-1110
10.1002/chem.201303215