Mayr's Database of Reactivity Parameters

Isochalkogenoureas

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Isochalkogenoureas

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
O-DHPB (in CH2Cl2)
C10H10N2O *
 dichloromethane

N  Param.: 13.31

sN Param.: 0.69		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
O-HyperBTM (in CH2Cl2)
C19H20N2O *
 dichloromethane

N  Param.: 13.01

sN Param.: 0.73		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Te-BTM (in CH2Cl2)
C15H12N2Te *
 dichloromethane

N  Param.: 14.62

sN Param.: 0.66		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-DHPB (in CH2Cl2)
C10H10N2Se *
 dichloromethane

N  Param.: 15.16

sN Param.: 0.66		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-tetramisole (Se-TM) (in CH2Cl2)
C11H12N2Se *
 dichloromethane

N  Param.: 15.26

sN Param.: 0.60		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-BTM (in CH2Cl2)
C15H12N2Se *
 dichloromethane

N  Param.: 14.27

sN Param.: 0.63		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-HBTM (in CH2Cl2)
C16H14N2Se *
 dichloromethane

N  Param.: 14.42

sN Param.: 0.67		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-HyperBTM (in DCM)
C19H20N2Se *
 dichloromethane

N  Param.: 16.11

sN Param.: 0.58		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-HyperBTM (in MeCN)
C19H20N2Se *
 MeCN

N  Param.: 15.84

sN Param.: 0.57		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865
Se-HyperBTM (in THF)
C19H20N2Se *
 THF

N  Param.: 14.19

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2025, 64, e202514865
10.1002/anie.202514865