Mayr's Database of Reactivity Parameters

Arylating Boron Compounds

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Alkyl, Alkenyl and Aryl Boron Compounds » Arylating Boron Compounds

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
lithium (5-methylthiophen-2-yl)(4-(dimethylamino)phenyl)pinacolborate
C19H27BLiNO2S *
 MeCN

N  Param.: 8.02

sN Param.: 0.89		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium bis(5-methylthiophen-2-yl)pinacolborate
C16H22BLiO2S2 *
 MeCN

N  Param.: 7.67

sN Param.: 0.87		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium (5-methylfuran-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate
C18H21BF3LiO3 *
 MeCN

N  Param.: 8.13

sN Param.: 0.85		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)glycolborate
C15H12BF6LiO2S *
 MeCN

N  Param.: 11.23

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)neopentylglycolborate
C18H18BF6LiO2S *
 MeCN

N  Param.: 10.13

sN Param.: 0.91		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)neopentylglycolborate
C17H19BF3LiO2S *
 MeCN

N  Param.: 11.85

sN Param.: 0.72		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)catecholglycolborate
C18H13BF3LiO2S *
 MeCN

N  Param.: 6.50

sN Param.: 0.77		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562