Mayr's Database of Reactivity Parameters

Desoxy-Breslow intermediates

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Breslow intermediates
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
Desoxy Breslow intermediate 2a
*
 THF

N  Param.: 17.12

sN Param.: 0.80		***Angew. Chem. Int. Ed. 2012, 51, 6231-6235
10.1002/anie.201202327
Desoxy Breslow intermediate 2a
*
 DMSO

N  Param.: 17.41

sN Param.: 0.74		***Angew. Chem. Int. Ed. 2012, 51, 6231-6235
10.1002/anie.201202327
Desoxy Breslow intermediate 2a'
*
 THF

N  Param.: 14.45

sN Param.: 0.71		***Angew. Chem. Int. Ed. 2012, 51, 6231-6235
10.1002/anie.201202327
Desoxy Breslow intermediate 2b
*
 THF

N  Param.: 13.91

sN Param.: 0.64		***Angew. Chem. Int. Ed. 2012, 51, 6231-6235
10.1002/anie.201202327
Desoxy Breslow intermediate 2b'
*
 THF

N  Param.: 11.42

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2012, 51, 6231-6235
10.1002/anie.201202327
Desoxy Breslow intermediate 2c'
*
 THF

N  Param.: 12.75

sN Param.: 0.71		***Angew. Chem. Int. Ed. 2012, 51, 6231-6235
10.1002/anie.201202327
Dexoxy Breslow intermediate 6
*
 THF

N  Param.: 15.58

sN Param.: 0.57		***Angew. Chem. Int. Ed. 2012, 51, 10408-10412
10.1002/anie.201204524