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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40Found 1711 molecules, page 36 of 86
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
3,5-dinitrobenzoate (in MeCN)
*
 MeCN

N  Param.: 14.90

sN Param.: 0.71		**J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
p-quinone (C-H)
C6H4O2*

E Param.: -16.19

**J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C17H20BF6LiO2*
 MeCN

N  Param.: 8.71

sN Param.: 0.80		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
cycloheptatriene
C7H8*
 dichloromethane

N  Param.: 0.52

sN Param.: 0.97		*J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
67% water/33% MeCN (v/v)
H2O*
 water-MeCN mix

N  Param.: 5.05

sN Param.: 0.90		***J. Am. Chem. Soc. 2004, 126, 5174-5181
10.1021/ja031828z
anion of 2-nitropropane (in 91M9AN)
C3H6NO2-*
 MeOH-MeCN mix

N  Param.: 12.20

sN Param.: 0.71		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
glycylglycylglycine (anionic, in water)
C6H10N3O4*
 water

N  Param.: 12.26

sN Param.: 0.63		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
bh 6i
*

E Param.: -19.10

**Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487
THTP (3,5,6,7-tetrahydro-2H-thiazolo[3,2-a]pyrimidine)
*
 dichloromethane

N  Param.: 14.45

sN Param.: 0.78		***J. Org. Chem. 2011, 76, 5104-5112
10.1021/jo200803x
SO3(2-) (in water)
O3S*
 water

N  Param.: 16.83

sN Param.: 0.56		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
gamma-aminobutyric acid (anionic, in water)
C4H8NO2*
 water

N  Param.: 13.55

sN Param.: 0.56		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
1-methoxy-2-methyl-1-(trimethylsiloxy)propene (in MeCN)
*
 MeCN

N  Param.: 9.11

sN Param.: 0.88		***J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)pinacolborate
C18H21BF3LiO2S*
 MeCN

N  Param.: 6.24

sN Param.: 1.00		**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
chloride (in 40% aq MeCN)
Cl*
 water-MeCN mix

N  Param.: 11.30

sN Param.: 0.60		*J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran (in MeCN)
*
 MeCN

N  Param.: 10.52

sN Param.: 0.78		***J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x
2-sulfidoacetate (in water)
C2H2O2S*
 water

N  Param.: 22.62

sN Param.: 0.43		***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
methylenecyclobutane
C5H8*
 dichloromethane

N  Param.: 1.65

sN Param.: 0.90		*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclohepta-1,3,5-trienyl-Fe(CO)3
*
 dichloromethane

N  Param.: 3.42

sN Param.: 0.94		***J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
4,4-dimethyl-glutarimide anion (in DMSO)
*
 DMSO

N  Param.: 17.52

sN Param.: 0.63		***J. Org. Chem. 2010, 75, 5250-5258
10.1021/jo1009883
Dexoxy Breslow intermediate 6
*
 THF

N  Param.: 15.58

sN Param.: 0.57		***Angew. Chem. Int. Ed. 2012, 51, 10408-10412
10.1002/anie.201204524

News

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  • 01/30/26:
    Isochalcogenoureas (O, S, Se & Te derivatives) have been added (Angew. Chem. Int. Ed. 2025, 64, e202514865).
  • 01/30/25:
    Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
  • 05/22/24:
    Lactone enolates have been added (JOC 2024, 89, 6915-6928).
  • 11/13/24:
    2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
  • 05/21/24:
    Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
  • 10/19/23:
    Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
  • 09/28/23:
    Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
  • 07/05/23:
    S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
  • 03/16/23:
    Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
  • 01/30/23:
    NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
  • 09/20/22:
    Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
  • 01/30/23:
    Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
  • 01/30/23:
    Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
  • 01/30/23:
    Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
  • 04/13/21:
    Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
  • 05/21/21:
    Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
  • 05/06/20:
    Heteroallenes added (JACS 2020, 142, 8383-8402).
  • 01/27/20:
    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
  • 01/30/23:
    Phenolates added (JOC 2019, 84, 8837-8858)
  • 04/24/18:
    Ketones added (JACS 2018, 140, 5500).
  • 11/03/17:
    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).