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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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21 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29Found 1683 molecules, page 25 of 85
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
6-(julolidin-9-yl)fulvene
C18H19N*
 MeCN

N  Param.: 7.79

sN Param.: 1.06		***Eur. J. Org. Chem. 2009, , 1202-1206
10.1002/ejoc.200801099
Ph3P=CH-CO2Et
*
 dichloromethane

N  Param.: 12.79

sN Param.: 0.77		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
Ph3P=CH-CO2Et (in DMSO)
*
 DMSO

N  Param.: 12.21

sN Param.: 0.62		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
Ph3P=C(CH3)-CO2Et
*
 dichloromethane

N  Param.: 13.09

sN Param.: 0.73		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
Ph3P=CH-CN
*
 dichloromethane

N  Param.: 12.29

sN Param.: 0.75		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
Ph3P=CH-COPh
*
 dichloromethane

N  Param.: 9.54

sN Param.: 0.97		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
(EtO)2P(O)CH(-)CO2Et (in DMSO)
*
 DMSO

N  Param.: 19.23

sN Param.: 0.65		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
(EtO)2P(O)CH(-)CN (in DMSO)
*
 DMSO

N  Param.: 18.57

sN Param.: 0.66		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
Ph2P(O)CH(-)CO2Et (in DMSO)
*
 DMSO

N  Param.: 19.20

sN Param.: 0.69		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
Ph2P(O)CH(-)CN (in DMSO)
*
 DMSO

N  Param.: 18.69

sN Param.: 0.72		***J. Am. Chem. Soc. 2009, 131, 704-714
10.1021/ja8056216
(4-Br-C6H4)-(CO)-CH=SMe2
*
 dichloromethane

N  Param.: 11.95

sN Param.: 0.76		***Angew. Chem. Int. Ed. 2009, 48, 5034-5037
10.1002/anie.200900933
2-aminobutan-1-ol (in DMSO)
*
 DMSO

N  Param.: 14.39

sN Param.: 0.67		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
benzylamine (in DMSO)
*
 DMSO

N  Param.: 15.28

sN Param.: 0.65		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
1-aminopropan-2-ol (in DMSO)
*
 DMSO

N  Param.: 15.47

sN Param.: 0.65		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
diethanolamine (in DMSO)
*
 DMSO

N  Param.: 15.51

sN Param.: 0.70		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
ethanolamine (in DMSO)
*
 DMSO

N  Param.: 16.07

sN Param.: 0.61		***J. Am. Chem. Soc. 2009, 131, 11392-11401
10.1021/ja903207b
2-phenyl-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 9.72

sN Param.: 0.72		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-(p-anisyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.01

sN Param.: 0.72		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-(p-tolyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.14

sN Param.: 0.70		***Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
6-methoxy-quinoline (in MeCN)
*
 MeCN

N  Param.: 10.86

sN Param.: 0.66		***J. Org. Chem. 2009, 74, 7157-7164
10.1021/jo901670w

News

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  • 01/30/25:
    Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
  • 05/22/24:
    Lactone enolates have been added (JOC 2024, 89, 6915-6928).
  • 11/13/24:
    2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
  • 05/21/24:
    Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
  • 10/19/23:
    Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
  • 09/28/23:
    Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
  • 07/05/23:
    S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
  • 03/16/23:
    Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
  • 01/30/23:
    NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
  • 09/20/22:
    Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
  • 01/30/23:
    Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
  • 01/30/23:
    Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
  • 01/30/23:
    Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
  • 04/13/21:
    Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
  • 05/21/21:
    Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
  • 05/06/20:
    Heteroallenes added (JACS 2020, 142, 8383-8402).
  • 01/27/20:
    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
  • 01/30/23:
    Phenolates added (JOC 2019, 84, 8837-8858)
  • 04/24/18:
    Ketones added (JACS 2018, 140, 5500).
  • 11/03/17:
    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).