C-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
p-tosylmethyl isocyanide (TosMIC)	dichloromethane	N Param.: 3.50 s_N Param.: 0.76	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
4-cyanophenyl isocyanide	dichloromethane	N Param.: 3.57 s_N Param.: 0.72	Angew. Chem. Int. Ed. 2007, 46, 3563-3566 10.1002/anie.200605205
anisole	dichloromethane	N Param.: -1.18 s_N Param.: 1.20	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
anion of 4-nitrobenzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 14.49 s_N Param.: 0.86	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-cyanobenzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 16.28 s_N Param.: 0.75	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 17.33 s_N Param.: 0.74	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of benzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 18.67 s_N Param.: 0.68	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 19.35 s_N Param.: 0.67	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 18.24 s_N Param.: 0.66	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 19.49 s_N Param.: 0.63	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b