Mayr's Database of Reactivity Parameters

Peroxy anions

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Peroxy anions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
4-methoxyperoxybenzoate (in H2O)
C8H7O4 *
 water

N  Param.: 17.84

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3-chloro-4-methoxyperoxybenzoate (in H2O)
C8H6ClO4 *
 water

N  Param.: 18.56

sN Param.: 0.48		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
peroxybenzoate (in H2O)
C7H5O3 *
 water

N  Param.: 18.57

sN Param.: 0.43		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
beta-piperidinium-peroxypropionate
*
 water

N  Param.: 13.94

sN Param.: 0.62		 *** Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
peroxy-beta-alanate
*
 water

N  Param.: 14.07

sN Param.: 0.56		 *** Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
peroxy-GABA
*
 water

N  Param.: 14.33

sN Param.: 0.57		 *** Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158