Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
((4-methoxyphenyl)sulfonyl)(pyridin-4-yl)amide (Ph4P+) (in CH2Cl2)	dichloromethane	N Param.: 19.63 s_N Param.: 0.65	J. Am. Chem. Soc. 2025, 147, 5043-5050 10.1021/jacs.4c14825
pyridin-4-yl((trifluoromethyl)sulfonyl)amide (Ph4P+) (in MeCN)	MeCN	N Param.: 16.38 s_N Param.: 0.60	J. Am. Chem. Soc. 2025, 147, 5043-5050 10.1021/jacs.4c14825
((4-methoxyphenyl)sulfonyl)(pyridin-4-yl)amide (Ph4P+) (in MeCN)	MeCN	N Param.: 17.28 s_N Param.: 0.65	J. Am. Chem. Soc. 2025, 147, 5043-5050 10.1021/jacs.4c14825
pyridin-4-yl((4-(trifluoromethyl)phenyl)sulfonyl)amide (Ph4P+) (in MeCN)	MeCN	N Param.: 19.51 s_N Param.: 0.47	J. Org. Chem. 2025, 90, 2298-2306 10.1021/acs.joc.4c02668
pyridin-4-yl(tosyl)amide (Ph4P+) (in MeCN)	MeCN	N Param.: 17.19 s_N Param.: 0.64	J. Org. Chem. 2025, 90, 2298-2306 10.1021/acs.joc.4c02668
pyridin-4-yl((trifluoromethyl)sulfonyl)amide (Bu4P+) (in MeCN)	MeCN	N Param.: 16.48 s_N Param.: 0.60	J. Org. Chem. 2025, 90, 2298-2306 10.1021/acs.joc.4c02668
pyridin-4-yl((trifluoromethyl)sulfonyl)amide (Bu4N+) (in MeCN)	MeCN	N Param.: 16.68 s_N Param.: 0.59	J. Org. Chem. 2025, 90, 2298-2306 10.1021/acs.joc.4c02668
50% water/50% MeCN (v/v)	water-MeCN mix	N Param.: 5.05 s_N Param.: 0.89	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
O-DHPB (in CH2Cl2)	dichloromethane	N Param.: 13.31 s_N Param.: 0.69	Angew. Chem. Int. Ed. 2025, 64, e202514865 10.1002/anie.202514865
O-HyperBTM (in CH2Cl2)	dichloromethane	N Param.: 13.01 s_N Param.: 0.73	Angew. Chem. Int. Ed. 2025, 64, e202514865 10.1002/anie.202514865