Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
dipp Imd boronate
*
 dichloromethane

N  Param.: 9.55

sN Param.: 0.81		 *** Org. Lett. 2012, 14, 82-85
10.1021/ol202836p
Me2 Imd boronate
*
 dichloromethane

N  Param.: 11.88

sN Param.: 0.71		 *** Org. Lett. 2012, 14, 82-85
10.1021/ol202836p
imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.09

sN Param.: 0.51		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.03

sN Param.: 0.50		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-methyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 21.29

sN Param.: 0.51		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2,4-dimethyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 20.69

sN Param.: 0.60		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-nitro-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 14.81

sN Param.: 0.71		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
2-formyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 16.06

sN Param.: 0.68		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
4-formyl-imidazole anion (in DMSO)
*
 DMSO

N  Param.: 16.40

sN Param.: 0.67		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411
benzimidazole anion (in DMSO)
*
 DMSO

N  Param.: 19.13

sN Param.: 0.55		 *** Chem. Eur. J. 2012, 18, 127-137
10.1002/chem.201102411