Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

P-Ylides

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Ylides
Found 7 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

Ph3P=CH-CO2Et
dichloromethaneN  Parameter: 12.79
sN Parameter: 0.77
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
image of molecule

Ph3P=CH-CO2Et (in DMSO)
DMSON  Parameter: 12.21
sN Parameter: 0.62
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
image of molecule

Ph3P=C(CH3)-CO2Et
dichloromethaneN  Parameter: 13.09
sN Parameter: 0.73
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
image of molecule

Ph3P=CH-CN
dichloromethaneN  Parameter: 12.29
sN Parameter: 0.75
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
image of molecule

Ph3P=CH-COPh
dichloromethaneN  Parameter: 9.54
sN Parameter: 0.97
***J. Am. Chem. Soc. 2009, 131, 704-714
DOI: 10.1021/ja8056216
image of molecule

Ph3P=CH-CHO (in MeCN)
MeCNN  Parameter: 9.09
sN Parameter: 0.74
***J. Am. Chem. Soc. 2016, 138, 11272-11281
DOI: 10.1021/jacs.6b06264
image of molecule

Ph3P=CH-C(O)Me (in MeCN)
MeCNN  Parameter: 10.27
sN Parameter: 0.83
***J. Am. Chem. Soc. 2016, 138, 11272-11281
DOI: 10.1021/jacs.6b06264