Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
9-MeS-HyperBTM
C20H22N2S2 *
dichloromethane

N  Param.: 13.49

sN Param.: 0.78
*** ChemistryEurope 2026, 4, e202500434
10.1002/ceur.202500434
9-Me-HyperBTM
C20H22N2S *
dichloromethane

N  Param.: 14.76

sN Param.: 0.67
*** ChemistryEurope 2026, 4, e202500434
10.1002/ceur.202500434
7-PivO-HyperBTM
C24H28N2O2S *
dichloromethane

N  Param.: 14.49

sN Param.: 0.66
*** ChemistryEurope 2026, 4, e202500434
10.1002/ceur.202500434
7-Ms-HyperBTM
C20H22N2O2S2 *
dichloromethane

N  Param.: 12.52

sN Param.: 0.75
*** ChemistryEurope 2026, 4, e202500434
10.1002/ceur.202500434
HyperNTM
C23H22N2S *
dichloromethane

N  Param.: 14.47

sN Param.: 0.72
*** ChemistryEurope 2026, 4, e202500434
10.1002/ceur.202500434
HyperPTM
C27H24N2S *
dichloromethane

N  Param.: 13.43

sN Param.: 0.79
*** ChemistryEurope 2026, 4, e202500434
10.1002/ceur.202500434
2-(1-azidovinyl)naphthalene (in Cyrene)
C12H9N3 *
Cyrene (TM)

N  Param.: 6.00

sN Param.: 0.90
*** Chem. Commun. 2026, 62, 5041-5045
10.1039/d6cc00190d
1-(TBDMSO)-buta-1,3-diene
C10H20OSi *
dichloromethane

N  Param.: 4.78

sN Param.: 1.00
* Org. Chem. Front. 2026, AdvArticle,
10.1039/d6qo01106c
2-trimethylsiloxy-cyclohexa-1,3-diene
C9H16OSi *
dichloromethane

N  Param.: 7.53

sN Param.: 0.87
*** Org. Chem. Front. 2026, AdvArticle,
10.1039/d6qo01106c
2-trimethylsiloxy-cyclopentadiene
C8H14OSi *
dichloromethane

N  Param.: 7.93

sN Param.: 1.00
*** Org. Chem. Front. 2026, AdvArticle,
10.1039/d6qo01106c