Mayr's Database of Reactivity Parameters

Nucleophiles

96 | 97 | 98 | 99 | 100 | 101 | 102 | 103 | 104 Found 1357 molecules, displaying page 100 of 136 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C26H37N2P*
 MeCN

N  Param.: 19.85

sN Param.: 0.34		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphosphinane (in MeCN)
C11H25N2P*
 MeCN

N  Param.: 13.46

sN Param.: 0.52		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphospholidine (in MeCN)
C10H23N2P*
 MeCN

N  Param.: 18.74

sN Param.: 0.47		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-dimesityl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C20H25N2P*
 MeCN

N  Param.: 17.68

sN Param.: 0.68		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
Ph3P=CH-CHO (in MeCN)
C20H17OP*
 MeCN

N  Param.: 9.09

sN Param.: 0.74		***J. Am. Chem. Soc. 2016, 138, 11272-11281
10.1021/jacs.6b06264
Ph3P=CH-C(O)Me (in MeCN)
C21H19OP*
 MeCN

N  Param.: 10.27

sN Param.: 0.83		***J. Am. Chem. Soc. 2016, 138, 11272-11281
10.1021/jacs.6b06264
p-nitrophenolate (in MeCN)
C6H4NO3*
 MeCN

N  Param.: 15.14

sN Param.: 0.82		***J. Org. Chem. 2019, 84, 8837-8858
10.1021/acs.joc.9b01485
o-nitrophenolate (in MeCN)
C6H4NO3*
 MeCN

N  Param.: 15.83

sN Param.: 0.80		***J. Org. Chem. 2019, 84, 8837-8858
10.1021/acs.joc.9b01485
m-nitrophenolate (in MeCN)
C6H4NO3*
 MeCN

N  Param.: 25.51

sN Param.: 0.43		***J. Org. Chem. 2019, 84, 8837-8858
10.1021/acs.joc.9b01485
p-cyanophenolate (in MeCN)
C7H4KNO*
 MeCN

N  Param.: 19.58

sN Param.: 0.59		**J. Org. Chem. 2019, 84, 8837-8858
10.1021/acs.joc.9b01485