Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
4-(dimethylamino)pyridine (in 91M9AN)	MeOH-MeCN mix	N Param.: 13.20 s_N Param.: 0.67	Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941
anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 18.24 s_N Param.: 0.66	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 19.49 s_N Param.: 0.63	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)	MeOH-MeCN mix	N Param.: 20.72 s_N Param.: 0.58	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
n-propanolate (in propan-1-ol)	nPrOH	N Param.: 16.03 s_N Param.: 0.70	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
91% n-propanol/9% MeCN (v/v)	nPrOH-MeCN mix	N Param.: 7.05 s_N Param.: 0.80	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
n-propanolate (in 91nPr9AN)	nPrOH-MeCN mix	N Param.: 16.73 s_N Param.: 0.63	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
azide ion (in 91nPr9AN)	nPrOH-MeCN mix	N Param.: 16.70 s_N Param.: 0.73	J. Phys. Org. Chem. 2006, 19, 706-713 10.1002/poc.1063
trifluoroethanol	TFE	N Param.: 1.11 s_N Param.: 0.96	J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b
chloride (in CF3CH2OH)	TFE	N Param.: 10.30 s_N Param.: 0.60	J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n