Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
Ph3P=CH-CHO (in MeCN)	MeCN	N Param.: 9.09 s_N Param.: 0.74	J. Am. Chem. Soc. 2016, 138, 11272-11281 10.1021/jacs.6b06264
Ph3P=CH-CN	dichloromethane	N Param.: 12.29 s_N Param.: 0.75	J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216
Ph3P=CH-CO2Et	dichloromethane	N Param.: 12.79 s_N Param.: 0.77	J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216
Ph3P=CH-CO2Et (in DMSO)	DMSO	N Param.: 12.21 s_N Param.: 0.62	J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216
Ph3P=CH-COPh	dichloromethane	N Param.: 9.54 s_N Param.: 0.97	J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216
phenolate (in DMF)	DMF	N Param.: 18.86 s_N Param.: 0.89	J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485
phenolate (in DMSO)	DMSO	N Param.: 19.86 s_N Param.: 0.71	J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485
phenolate (in MeCN)	MeCN	N Param.: 18.53 s_N Param.: 0.85	J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485
phenylacetylene	dichloromethane	N Param.: -0.04 s_N Param.: 0.77	Angew. Chem. Int. Ed. 2014, 53, 4968-4971 10.1002/anie.201402055
phenylalanine (anionic, in water)	water	N Param.: 14.12 s_N Param.: 0.53	Org. Biomol. Chem. 2007, 5, 3814-3820 10.1039/b713778h