Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
toluene   |
dichloromethane | N Param.: -4.36 sN Param.: 1.77 |
 |
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
m-xylene  |
dichloromethane | N Param.: -3.57 sN Param.: 2.08 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(E)-propenylbenzene  |
dichloromethane | N Param.: -0.49 sN Param.: 1.18 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
2-methylthiophene  |
dichloromethane | N Param.: 1.35 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
styrene  |
dichloromethane | N Param.: 0.78 sN Param.: 0.95 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1,3-dimethoxybenzene  |
dichloromethane | N Param.: 2.48 sN Param.: 1.09 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltrimethylsilane  |
dichloromethane | N Param.: 1.68 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
allyltriphenylstannane  |
dichloromethane | N Param.: 3.09 sN Param.: 0.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)trimethylsilane  |
dichloromethane | N Param.: 4.41 sN Param.: 0.96 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltributylstannane  |
dichloromethane | N Param.: 5.46 sN Param.: 0.89 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)tributylstannane  |
dichloromethane | N Param.: 7.48 sN Param.: 0.89 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
Danishefskys diene  |
dichloromethane | N Param.: 8.57 sN Param.: 0.84 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran  |
dichloromethane | N Param.: 10.61 sN Param.: 0.86 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
5-(trimethylsiloxy)-2,3-dihydrofuran  |
dichloromethane | N Param.: 12.56 sN Param.: 0.70 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
methylenecyclopentane  |
dichloromethane | N Param.: 2.82 sN Param.: 0.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methylfuran  |
dichloromethane | N Param.: 3.61 sN Param.: 1.11 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
N-methylpyrrole  |
dichloromethane | N Param.: 5.85 sN Param.: 1.03 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(trimethylsiloxy)cyclohexene  |
dichloromethane | N Param.: 5.21 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(trimethylsiloxy)propene  |
dichloromethane | N Param.: 5.41 sN Param.: 0.91 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-phenyl-1-(trimethylsiloxy)ethene  |
dichloromethane | N Param.: 6.22 sN Param.: 0.96 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(trimethylsiloxy)cyclopentene  |
dichloromethane | N Param.: 6.57 sN Param.: 0.93 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-phenoxy-1-(trimethylsiloxy)ethene  |
dichloromethane | N Param.: 8.23 sN Param.: 0.81 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(N-morpholino)cyclohexene  |
dichloromethane | N Param.: 11.40 sN Param.: 0.83 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(N-piperidino)cyclohexene  |
dichloromethane | N Param.: 13.36 sN Param.: 0.81 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(Z)-but-2-ene  |
dichloromethane | N Param.: -2.44 sN Param.: 1.09 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltriphenylsilane  |
dichloromethane | N Param.: -0.13 sN Param.: 1.21 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
3-methylanisole  |
dichloromethane | N Param.: 0.13 sN Param.: 1.27 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
phenylacetylene  |
dichloromethane | N Param.: -0.04 sN Param.: 0.77 |
|
Angew. Chem. Int. Ed. 2014, 53, 4968-4971 10.1002/anie.201402055 |
(triisopropylsiloxy)ethene  |
dichloromethane | N Param.: 3.44 sN Param.: 0.94 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)triphenylsilane  |
dichloromethane | N Param.: 4.17 sN Param.: 0.79 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(triisopropylsiloxy)propene  |
dichloromethane | N Param.: 5.38 sN Param.: 0.85 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
phenylsilane  |
dichloromethane | N Param.: 0.06 sN Param.: 0.71 |
|
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
triphenylsilane  |
dichloromethane | N Param.: 2.65 sN Param.: 0.72 |
|
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
dimethyl(phenyl)silane  |
dichloromethane | N Param.: 3.55 sN Param.: 0.75 |
|
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
triethylsilane  |
dichloromethane | N Param.: 3.58 sN Param.: 0.70 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
triphenylgermane  |
dichloromethane | N Param.: 3.99 sN Param.: 0.62 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
tributylsilane  |
dichloromethane | N Param.: 3.99 sN Param.: 0.73 |
|
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
triphenylstannane  |
dichloromethane | N Param.: 5.64 sN Param.: 0.59 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
tributylgermane  |
dichloromethane | N Param.: 5.92 sN Param.: 0.73 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
borane-triethylamine-complex  |
dichloromethane | N Param.: 8.90 sN Param.: 0.75 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
tributylstannane  |
dichloromethane | N Param.: 9.96 sN Param.: 0.55 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
cycloheptatriene  |
dichloromethane | N Param.: 0.52 sN Param.: 0.97 |
|
J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
1-(N-pyrrolidino)cyclopentene  |
dichloromethane | N Param.: 15.91 sN Param.: 0.86 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(N-piperidino)cyclopentene  |
dichloromethane | N Param.: 15.06 sN Param.: 0.82 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(N-pyrrolidino)cyclohexene  |
dichloromethane | N Param.: 14.91 sN Param.: 0.86 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(N-morpholino)cyclopentene  |
dichloromethane | N Param.: 13.41 sN Param.: 0.82 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(phenylmethylamino)cyclopentene  |
dichloromethane | N Param.: 12.90 sN Param.: 0.79 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
1-(phenylmethylamino)cyclohexene  |
dichloromethane | N Param.: 10.73 sN Param.: 0.81 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
morpholinoisobutylene  |
dichloromethane | N Param.: 10.04 sN Param.: 0.82 |
|
Chem. Eur. J. 2003, 9, 2209-2218 10.1002/chem.200204666 |
N-vinylcarbazole  |
dichloromethane | N Param.: 5.02 sN Param.: 0.94 |
|
Macromolecules 2002, 35, 5454-5458 10.1021/ma020306l |