Mayr's Database of Reactivity Parameters

Nucleophiles

16 | 17 | 18 | 19 | 20 | 21 | 22 | 23 | 24 Found 1323 molecules, displaying page 20 of 27 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)
C9H5F6O2S-*
 MeOH-MeCN mix

N  Param.: 20.72

sN Param.: 0.58		***J. Am. Chem. Soc. 2007, 129, 9753-9761
10.1021/ja072135b
DABCO (in MeCN)
C6H12N2*
 MeCN

N  Param.: 18.80

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2007, 46, 6176-6179
10.1002/anie.200701489
quinuclidine (in MeCN)
C7H13N*
 MeCN

N  Param.: 20.54

sN Param.: 0.60		***Angew. Chem. Int. Ed. 2007, 46, 6176-6179
10.1002/anie.200701489
glycine (anionic, in water)
C2H4NO2*
 water

N  Param.: 13.51

sN Param.: 0.58		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
alanine (anionic, in water)
C3H6NO2*
 water

N  Param.: 13.01

sN Param.: 0.58		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
valine (anionic, in water)
C5H10NO2*
 water

N  Param.: 13.65

sN Param.: 0.57		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
leucine (anionic, in water)
C6H12NO2*
 water

N  Param.: 14.01

sN Param.: 0.52		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
phenylalanine (anionic, in water)
C9H10NO2*
 water

N  Param.: 14.12

sN Param.: 0.53		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
proline (anionic, in water)
C5H8NO2*
 water

N  Param.: 18.08

sN Param.: 0.50		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
serine (anionic, in water)
C3H6NO3*
 water

N  Param.: 13.16

sN Param.: 0.55		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
threonine (anionic, in water)
C4H8NO3*
 water

N  Param.: 12.69

sN Param.: 0.60		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
asparagine (anionic, in water)
C4H7N2O3*
 water

N  Param.: 13.03

sN Param.: 0.53		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
glutamine (anionic, in water)
C5H9N2O3*
 water

N  Param.: 13.45

sN Param.: 0.54		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
arginine (betaine, in water)
C6H14N4O2*
 water

N  Param.: 12.96

sN Param.: 0.57		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
histidine (anionic, in water)
C6H8N3O2*
 water

N  Param.: 13.83

sN Param.: 0.54		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
aspartate (dianionic, in water)
C4H5NO4*
 water

N  Param.: 13.81

sN Param.: 0.53		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
glutamate (dianionic, in water)
C5H7NO4*
 water

N  Param.: 13.96

sN Param.: 0.54		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
cysteine (dianionic, in water, S-nucleophile!)
C3H5NO2S*
 water

N  Param.: 23.43

sN Param.: 0.42		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
methionine (anionic, in water)
C5H10NO2S*
 water

N  Param.: 13.16

sN Param.: 0.58		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
beta-alanine (anionic, in water)
C3H6NO2*
 water

N  Param.: 13.26

sN Param.: 0.58		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
gamma-aminobutyric acid (anionic, in water)
C4H8NO2*
 water

N  Param.: 13.55

sN Param.: 0.56		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
glycylglycine (anionic, in water)
C4H7N2O3*
 water

N  Param.: 12.91

sN Param.: 0.59		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
glycylglycylglycine (anionic, in water)
C6H10N3O4*
 water

N  Param.: 12.26

sN Param.: 0.63		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
cysteine (dianionic, in water)
C3H5NO2S*
 water

N  Param.: 23.43

sN Param.: 0.42		***Org. Biomol. Chem. 2007, 5, 3814-3820
10.1039/b713778h
Indole
C8H7N*
 dichloromethane

N  Param.: 5.55

sN Param.: 1.09		***J. Org. Chem. 2006, 71, 9088-9095
10.1021/jo0614339
N-methylindole
C9H9N*
 dichloromethane

N  Param.: 5.75

sN Param.: 1.23		***J. Org. Chem. 2006, 71, 9088-9095
10.1021/jo0614339
1,2-dimethylindole
C10H11N*
 dichloromethane

N  Param.: 6.54

sN Param.: 1.10		*J. Org. Chem. 2006, 71, 9088-9095
10.1021/jo0614339
anion of nitromethane (in 91M9AN)
CH2NO2-*
 MeOH-MeCN mix

N  Param.: 14.02

sN Param.: 0.61		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of nitroethane (in 91M9AN)
C2H4NO2-*
 MeOH-MeCN mix

N  Param.: 13.41

sN Param.: 0.67		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of 2-nitropropane (in 91M9AN)
C3H6NO2-*
 MeOH-MeCN mix

N  Param.: 12.20

sN Param.: 0.71		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of phenylnitromethane (in 91M9AN)
C7H6NO2-*
 MeOH-MeCN mix

N  Param.: 12.51

sN Param.: 0.67		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of p-tolylnitromethane (in 91M9AN)
C8H8NO2-*
 MeOH-MeCN mix

N  Param.: 13.58

sN Param.: 0.64		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of (4-nitrophenyl)nitromethane (in 91M9AN)
C7H5N2O4-*
 MeOH-MeCN mix

N  Param.: 14.05

sN Param.: 0.72		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of (3-nitrophenyl)nitromethane (in 91M9AN)
C7H5N2O4-*
 MeOH-MeCN mix

N  Param.: 14.75

sN Param.: 0.71		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of (4-cyanophenyl)nitromethane (in 91M9AN)
C8H5N2O2-*
 MeOH-MeCN mix

N  Param.: 13.92

sN Param.: 0.74		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of ethyl cyanoacetate (in 91M9AN)
C5H6NO2-*
 MeOH-MeCN mix

N  Param.: 18.59

sN Param.: 0.65		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of malononitrile (in 91M9AN)
C3HN2-*
 MeOH-MeCN mix

N  Param.: 18.21

sN Param.: 0.69		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of dimethyl malonate (in 91M9AN)
C5H7O4-*
 MeOH-MeCN mix

N  Param.: 18.24

sN Param.: 0.64		***Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
azide ion (in 91M9AN)
N3-*
 MeOH-MeCN mix

N  Param.: 14.54

sN Param.: 0.82		***J. Phys. Org. Chem. 2006, 19, 706-713
10.1002/poc.1063
azide ion (in 91E9AN)
N3-*
 EtOH-MeCN mix

N  Param.: 16.30

sN Param.: 0.73		***J. Phys. Org. Chem. 2006, 19, 706-713
10.1002/poc.1063
azide ion (in 91nPr9AN)
N3-*
 nPrOH-MeCN mix

N  Param.: 16.70

sN Param.: 0.73		***J. Phys. Org. Chem. 2006, 19, 706-713
10.1002/poc.1063
azide ion (in 91iPr9AN)
N3-*
 iPrOH-MeCN mix

N  Param.: 17.07

sN Param.: 0.71		***J. Phys. Org. Chem. 2006, 19, 706-713
10.1002/poc.1063
azide ion (in DMSO)
N3-*
 DMSO

N  Param.: 20.50

sN Param.: 0.59		***J. Phys. Org. Chem. 2006, 19, 706-713
10.1002/poc.1063
azide ion (in 45M55AN)
N3-*
 MeOH-MeCN mix

N  Param.: 15.01

sN Param.: 0.80		***J. Phys. Org. Chem. 2006, 19, 706-713
10.1002/poc.1063
pyrrolidine (in 91M9AN)
C4H9N*
 MeOH-MeCN mix

N  Param.: 15.97

sN Param.: 0.63		***Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542
piperidine (in 91M9AN)
C5H11N*
 MeOH-MeCN mix

N  Param.: 15.63

sN Param.: 0.64		***Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542
morpholine (in 91M9AN)
C4H9NO*
 MeOH-MeCN mix

N  Param.: 15.40

sN Param.: 0.64		***Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542
diethanolamine (in 91M9AN)
C4H11NO2*
 MeOH-MeCN mix

N  Param.: 13.71

sN Param.: 0.67		***Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542
hydrazine (in 91M9AN)
H4N2*
 MeOH-MeCN mix

N  Param.: 13.47

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542
trimethyl phosphite (in 91M9AN)
C3H9O3P*
 MeOH-MeCN mix

N  Param.: 9.04

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2006, 45, 3869-3874
10.1002/anie.200600542