Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
67% water/33% MeCN (v/v)	water-MeCN mix	N Param.: 5.05 s_N Param.: 0.90	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
50% water/50% MeCN (v/v)	water-MeCN mix	N Param.: 5.05 s_N Param.: 0.89	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
1-(trimethylsiloxy)-3,4-dihydronaphthalene (in MeCN)	MeCN	N Param.: 5.06 s_N Param.: 0.91	Synthesis 2019, 51, 1157-1170 10.1055/s-0037-1611634
1-(tris(trimethylsilyl)siloxy)cyclohexene	dichloromethane	N Param.: 5.07 s_N Param.: 0.91	Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e
Cp2Zr(CH2Ph)2 - Dibenzylzirconocene	dichloromethane	N Param.: 5.10 s_N Param.: 1.03	Chem. Eur. J. 2016, 22, 11196-11200 10.1002/chem.201602452
(2-methylallyl)triphenylstannane	dichloromethane	N Param.: 5.13 s_N Param.: 0.90	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
91% water/9% MeCN (v/v)	water-MeCN mix	N Param.: 5.16 s_N Param.: 0.91	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
N-benzyl-N-(but-1-yn-1-yl)-4-methylbenzenesulfonamide	dichloromethane	N Param.: 5.16 s_N Param.: 0.85	Angew. Chem. Int. Ed. 2014, 53, 4968-4971 10.1002/anie.201402055
4-(1-azidovinyl)-1,1'-biphenyl	dichloromethane	N Param.: 5.17 s_N Param.: 0.86	Chem. Commun. 2026, 62, 5041-5045 10.1039/d6cc00190d
(Z)-1-phenyl-1-(trimethylsiloxy)propene (in MeCN)	MeCN	N Param.: 5.18 s_N Param.: 0.94	Synthesis 2019, 51, 1157-1170 10.1055/s-0037-1611634