Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
3-acetyl-2-oxotetrahydro-2H-pyran-3-ide (in DMSO)	DMSO	N Param.: 17.00 s_N Param.: 0.74	Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107
[H-B(C6F5)3]- [NEt4]+	MeCN	N Param.: 10.04 s_N Param.: 0.73	Angew. Chem. Int. Ed. 2015, 54, 14508-14512 10.1002/anie.201507298
[H-B(2,4,6-F3C6H2)3]- [NEt4]+	MeCN	N Param.: 14.13 s_N Param.: 0.61	Angew. Chem. Int. Ed. 2015, 54, 14508-14512 10.1002/anie.201507298
[H-B(2,6-F2C6H3)3]- [NEt4]+	MeCN	N Param.: 13.97 s_N Param.: 0.66	Angew. Chem. Int. Ed. 2015, 54, 14508-14512 10.1002/anie.201507298
phenylacetylene	dichloromethane	N Param.: -0.04 s_N Param.: 0.77	Angew. Chem. Int. Ed. 2014, 53, 4968-4971 10.1002/anie.201402055
2-(trimethylsilyl)propene	dichloromethane	N Param.: -1.46 s_N Param.: 1.05	Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215
2-(pentamethyldisilyl)propene	dichloromethane	N Param.: -0.26 s_N Param.: 0.95	Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215
2-(tris(trimethylsilyl)silyl)propene	dichloromethane	N Param.: -0.31 s_N Param.: 0.99	Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215
alpha-(trimethylsilyl)styrene	dichloromethane	N Param.: -1.13 s_N Param.: 1.46	Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215
alpha-(pentamethyldisilyl)styrene	dichloromethane	N Param.: 0.61 s_N Param.: 1.01	Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215