Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-tritylpyrrolidine	MeCN	N Param.: 9.16 s_N Param.: 1.39	J. Am. Chem. Soc. 2020, 142, 1526-1547 10.1021/jacs.9b11877
20% ethanol/80% MeCN (v/v)	EtOH-MeCN mix	N Param.: 5.77 s_N Param.: 0.92	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
20% methanol/80% MeCN (v/v)	MeOH-MeCN mix	N Param.: 6.04 s_N Param.: 0.94	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
20% water/80% acetone (v/v)	water-acetone mix	N Param.: 5.77 s_N Param.: 0.87	Angew. Chem. Int. Ed. 2004, 43, 2302-2305 10.1002/anie.200353468
20% water/80% MeCN (v/v)	water-MeCN mix	N Param.: 5.02 s_N Param.: 0.89	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
20% water/80%EtOH (v/v)	water-EtOH mix	N Param.: 6.68 s_N Param.: 0.85	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
20% water/80%TFE (v/v)	water-TFE mix	N Param.: 3.20 s_N Param.: 0.88	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)	DMSO	N Param.: 16.06 s_N Param.: 0.69	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
3% water/97% HFIP (w/w)	water-HFIP mix	N Param.: -1.19 s_N Param.: 1.08	J. Phys. Org. Chem. 2013, 26, 59-63 10.1002/poc.3064
3,3,3-trifluoro-2-(trimethylsiloxy)propene	dichloromethane	N Param.: -2.94 s_N Param.: 1.11	Org. Lett. 2012, 14, 3990-3993 10.1021/ol301766w