Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
Meldrum's acid iodonium ylide (in CH2Cl2)	dichloromethane	N Param.: 4.36 s_N Param.: 1.06	J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768
MeO-Breslow 1a	THF	N Param.: 14.77 s_N Param.: 0.80	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeO-Breslow 1b	THF	N Param.: 10.45 s_N Param.: 0.81	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeO-Breslow 1c	THF	N Param.: 16.61 s_N Param.: 0.68	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeO-Breslow 1e	THF	N Param.: 15.65 s_N Param.: 0.52	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeSO-CH-CO2Et (in DMSO)	DMSO	N Param.: 20.61 s_N Param.: 0.64	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
MeSO2-CH-CO2Et (in DMSO)	DMSO	N Param.: 18.00 s_N Param.: 0.66	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
methanesulfonamide anion (in DMSO)	DMSO	N Param.: 18.61 s_N Param.: 0.53	J. Org. Chem. 2010, 75, 5250-5258 10.1021/jo1009883
methanol	MeOH	N Param.: 7.54 s_N Param.: 0.92	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
methanol (in MeCN)	MeCN	N Param.: 6.86 s_N Param.: 0.73	Bull. Chem. Soc. Jpn. 2018, 91, 523-530 10.1246/bcsj.20170360
methanolate (in 91M9AN)	MeOH-MeCN mix	N Param.: 14.51 s_N Param.: 0.68	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
methanolate (in methanol)	MeOH	N Param.: 15.78 s_N Param.: 0.56	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
methionine (anionic, in water)	water	N Param.: 13.16 s_N Param.: 0.58	Org. Biomol. Chem. 2007, 5, 3814-3820 10.1039/b713778h
methoxybis(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 17.29 s_N Param.: 0.70	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
methyl (cyclohexen-1-yl)prolinate (in MeCN)	MeCN	N Param.: 14.96 s_N Param.: 0.68	Angew. Chem. Int. Ed. 2010, 49, 9526-9529 10.1002/anie.201004344
methyl carbonate (in MeCN)	MeCN	N Param.: 16.03 s_N Param.: 0.64	Eur. J. Org. Chem. 2010, , 4205-4210 10.1002/ejoc.201000414
methyl diazoacetate	dichloromethane	N Param.: 4.68 s_N Param.: 0.94	J. Am. Chem. Soc. 2023, 145, 7416-7434 10.1021/jacs.2c13872
methyl glycinate (in water)	water	N Param.: 12.08 s_N Param.: 0.60	J. Org. Chem. 2007, 72, 3679-3688 10.1021/jo062586z
methyl L-prolinate	MeCN	N Param.: 14.75 s_N Param.: 0.82	J. Am. Chem. Soc. 2020, 142, 1526-1547 10.1021/jacs.9b11877
methyl(neopentyl)(phenyl)silane	dichloromethane	N Param.: 0.87 s_N Param.: 0.75	Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839