Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF)	THF	N Param.: 21.36 s_N Param.: 0.42	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF)	THF	N Param.: 20.78 s_N Param.: 0.61	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-5-methyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 24.86 s_N Param.: 0.52	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-5-(4-methoxyphenyl)-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 23.55 s_N Param.: 0.56	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 22.80 s_N Param.: 0.60	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-4-methylene-5-(4-(trifluoromethyl)phenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 22.30 s_N Param.: 0.49	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)	MeCN	N Param.: 19.85 s_N Param.: 0.34	Angew. Chem. Int. Ed. 2019, 58, 5983-5987 10.1002/anie.201901456
1,3,5-trimethylcyclohexa-1,4-diene (in CH2Cl2)	dichloromethane	N Param.: 4.95 s_N Param.: 0.79	J. Am. Chem. Soc. 2014, 136, 13863-13873 10.1021/ja507598y
1,3,5-trimethyl-2-methylene-1,2-dihydropyridine (in DMSO)	DMSO	N Param.: 21.16 s_N Param.: 0.59	Eur. J. Org. Chem. 2024, 27, e202400373 10.1002/ejoc.202400373
1,3,4-triphenyl-1H-1,2,4-triazol-4-ium-5-ide (in THF)	THF	N Param.: 14.07 s_N Param.: 0.84	Angew. Chem. Int. Ed. 2011, 50, 6915-6919 10.1002/anie.201102435
1,2-dimethylindole	dichloromethane	N Param.: 6.54 s_N Param.: 1.10	J. Org. Chem. 2006, 71, 9088-9095 10.1021/jo0614339
1,2-dimethylhydrazine (in MeCN)	MeCN	N Param.: 16.15 s_N Param.: 0.68	J. Org. Chem. 2012, 77, 8142-8155 10.1021/jo301497g
1,2-dihydronaphthalene (in MeCN)	MeCN	N Param.: -3.30 s_N Param.: 1.00	Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839
1,2-bis(trimethylsiloxy)cyclohexene	dichloromethane	N Param.: 4.46 s_N Param.: 1.15	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,2,5-trimethylpyrrole	MeCN	N Param.: 8.69 s_N Param.: 1.07	Eur. J. Org. Chem. 2008, , 2369-2374 10.1002/ejoc.200800092
1,2,4,5-tetramethylcyclohexa-1,4-diene (in CH2Cl2)	dichloromethane	N Param.: 4.27 s_N Param.: 0.86	J. Am. Chem. Soc. 2014, 136, 13863-13873 10.1021/ja507598y
1,2,3-trimethoxy-1,3-dioxopropan-2-ide (in DMSO)	DMSO	N Param.: 20.08 s_N Param.: 0.74	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
1,2,3,5,6,7-hexahydroimidazo[1,2-a]pyrimidine (TBN)	dichloromethane	N Param.: 16.15 s_N Param.: 0.73	ChemCatChem 2012, 4, 993-999 10.1002/cctc.201200143
1,1-dimethylsilolane	dichloromethane	N Param.: -3.86 s_N Param.: 1.10	Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839
1,1-dimethylsilinane	dichloromethane	N Param.: -2.40 s_N Param.: 1.10	Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839