Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles
1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 Found 568 molecules, displaying page 5 of 29 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of (phenylmethylenedisulfonyl)dibenzene (in DMSO)
C19H15O4S2*
 DMSO

N  Param.: 15.07

sN Param.: 0.79		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
anion of 1,2,3-triphenylpropane-1,3-dione (in DMSO)
C21H15O2*
 DMSO

N  Param.: 14.99

sN Param.: 0.83		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
barbiturate anion (in DMSO)
C4H3N2O3*
 DMSO

N  Param.: 15.59

sN Param.: 0.80		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
1,3-dimethylbarbiturate anion (in DMSO)
C6H7N2O3*
 DMSO

N  Param.: 17.46

sN Param.: 0.72		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
2-thiobarbiturate anion (in DMSO)
C4H3N2O2S*
 DMSO

N  Param.: 14.24

sN Param.: 0.82		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
1,3-diethyl-thiobarbiturate anion (in DMSO)
C8H11N2O2S*
 DMSO

N  Param.: 14.90

sN Param.: 0.80		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
C9H17BO2*
 dichloromethane

N  Param.: -0.64

sN Param.: 1.10		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
potassium allyltrifluoroborate (in MeCN)
C3H5BF3K*
 MeCN

N  Param.: 5.29

sN Param.: 0.87		**J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C17H20BF6LiO2*
 MeCN

N  Param.: 8.71

sN Param.: 0.80		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium 2-allyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C15H22BLiO2*
 MeCN

N  Param.: 11.20

sN Param.: 0.64		*J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C18H22BF6LiO2*
 MeCN

N  Param.: 9.49

sN Param.: 0.82		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
anion of diethyl 2-(isopropyl)malonate (in DMSO)
C10H17O4*
 DMSO

N  Param.: 18.74

sN Param.: 0.71		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-butylmalonate (in DMSO)
C11H19O4*
 DMSO

N  Param.: 23.00

sN Param.: 0.55		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-cyclohexylmalonate (in DMSO)
C13H21O4*
 DMSO

N  Param.: 19.23

sN Param.: 0.67		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-phenylmalonate (in DMSO)
C13H15O4*
 DMSO

N  Param.: 15.93

sN Param.: 0.99		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(4-nitrophenyl)malonate (in DMSO)
C13H14NO6*
 DMSO

N  Param.: 14.94

sN Param.: 0.96		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of triethyl methanetricarboxylate (in DMSO)
C10H15O6*
 DMSO

N  Param.: 15.33

sN Param.: 0.72		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(acetyl)malonate (in DMSO)
C9H13O5*
 DMSO

N  Param.: 13.83

sN Param.: 0.84		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(benzoyl)malonate (in DMSO)
C14H15O5*
 DMSO

N  Param.: 13.63

sN Param.: 0.80		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of 5-phenyl Meldrum's acid (in DMSO)
C12H11O4*
 DMSO

N  Param.: 11.54

sN Param.: 0.95		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107