Mayr's Database of Reactivity Parameters

C-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
methylenecyclobutane
C5H8 *
dichloromethane

N  Param.: 1.65

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclohexane
C7H12 *
dichloromethane

N  Param.: 1.16

sN Param.: 1.04
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
methylenecycloheptane
C8H14 *
dichloromethane

N  Param.: 2.24

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclooctane
C9H16 *
dichloromethane

N  Param.: 3.16

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclononane
C10H18 *
dichloromethane

N  Param.: 2.57

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclodecane
C11H20 *
dichloromethane

N  Param.: 2.82

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecycloundecane
C12H22 *
dichloromethane

N  Param.: 2.33

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclododecane
C13H24 *
dichloromethane

N  Param.: 1.52

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclopentadecane
C16H30 *
dichloromethane

N  Param.: 1.69

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-(bis(trimethylsiloxy)amino)propene
C9H23NO2Si2 *
dichloromethane

N  Param.: 4.76

sN Param.: 0.86
*** J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927