Mayr's Database of Reactivity Parameters

N-Ylides

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Ylides » N-Ylides

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-ethoxy-2-oxo-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO)
C9H12NO2 *
 DMSO

N  Param.: 26.71

sN Param.: 0.37		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
2-(diethylamino)-2-oxo-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO)
C11H17N2O *
 DMSO

N  Param.: 27.45

sN Param.: 0.38		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
cyano(pyridin-1-ium-1-yl)methanide (in DMSO)
C7H7N2 *
 DMSO

N  Param.: 25.94

sN Param.: 0.42		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
2-oxo-1-(pyridin-1-ium-1-yl)propan-1-ide (in DMSO)
C8H10NO *
 DMSO

N  Param.: 20.24

sN Param.: 0.60		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
2-oxo-2-phenyl-1-(pyridin-1-ium-1-yl)ethan-1-ide (in DMSO)
C13H12NO *
 DMSO

N  Param.: 19.46

sN Param.: 0.58		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
1-(4-(dimethylamino)pyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO)
C15H17N2O *
 DMSO

N  Param.: 21.61

sN Param.: 0.58		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
1-(3-chloropyridin-1-ium-1-yl)-2-oxo-2-phenylethan-1-ide (in DMSO)
C13H11ClNO *
 DMSO

N  Param.: 17.98

sN Param.: 0.63		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
2-oxo-2-phenyl-1-(quinolin-1-ium-1-yl)ethan-1-ide (in DMSO)
C17H14NO *
 DMSO

N  Param.: 19.38

sN Param.: 0.50		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h
1-(isoquinolin-2-ium-2-yl)-2-oxo-2-phenylethan-1-ide (in DMSO)
C17H14NO *
 DMSO

N  Param.: 20.08

sN Param.: 0.57		 *** J. Am. Chem. Soc. 2013, 135, 15216-15224
10.1021/ja407885h