Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
Me2S=CH-CN (in DMSO)
*
 DMSO

N  Param.: 16.23

sN Param.: 0.60		 *** Chem. Eur. J. 2010, 16, 8610-8614
10.1002/chem.201001455
MeSO2-CH-CO2Et (in DMSO)
*
 DMSO

N  Param.: 18.00

sN Param.: 0.66		 *** Chem. Eur. J. 2010, 16, 8610-8614
10.1002/chem.201001455
MeSO-CH-CO2Et (in DMSO)
*
 DMSO

N  Param.: 20.61

sN Param.: 0.64		 *** Chem. Eur. J. 2010, 16, 8610-8614
10.1002/chem.201001455
(cyclohexen-1-yl)prolinate (in MeCN)
*
 MeCN

N  Param.: 18.86

sN Param.: 0.70		 *** Angew. Chem. Int. Ed. 2010, 49, 9526-9529
10.1002/anie.201004344
1-(N-pyrrolidino)cyclohexene (in MeCN)
*
 MeCN

N  Param.: 16.42

sN Param.: 0.70		 *** Angew. Chem. Int. Ed. 2010, 49, 9526-9529
10.1002/anie.201004344
methyl (cyclohexen-1-yl)prolinate (in MeCN)
*
 MeCN

N  Param.: 14.96

sN Param.: 0.68		 *** Angew. Chem. Int. Ed. 2010, 49, 9526-9529
10.1002/anie.201004344
(4-Br-C6H4)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 13.78

sN Param.: 0.72		 *** J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
(C6H5)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 13.95

sN Param.: 0.69		 *** J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
(4-MeO-C6H4)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 14.48

sN Param.: 0.71		 *** J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749
(4-Me2N-C6H4)-(CO)-CH=SMe2 (in DMSO)
*
 DMSO

N  Param.: 15.68

sN Param.: 0.65		 *** J. Am. Chem. Soc. 2010, 132, 17894-17900
10.1021/ja1084749