Mayr's Database of Reactivity Parameters

Peroxy anions

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
3-chloro-4-methoxyperoxybenzoate (in H2O)
C8H6ClO4*
water

N  Param.: 18.56

sN Param.: 0.48
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
peroxybenzoate (in H2O)
C7H5O3*
water

N  Param.: 18.57

sN Param.: 0.43
***Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
beta-piperidinium-peroxypropionate
*
water

N  Param.: 13.94

sN Param.: 0.62
***Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
peroxy-beta-alanate
*
water

N  Param.: 14.07

sN Param.: 0.56
***Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
peroxy-GABA
*
water

N  Param.: 14.33

sN Param.: 0.57
***Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
HOO- (in water)
HO2*
water

N  Param.: 15.40

sN Param.: 0.55
***J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y