Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
chloride (in 50% aq MeCN)
Cl *
 water-MeCN mix

N  Param.: 12.00

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
chloride (in 60% aq MeCN)
Cl *
 water-MeCN mix

N  Param.: 12.00

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
chloride (in 80% aq MeCN)
Cl *
 water-MeCN mix

N  Param.: 13.30

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
chloride (in MeCN)
Cl *
 MeCN

N  Param.: 17.20

sN Param.: 0.60		 ** J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
chloride (in CF3CH2OH)
Cl *
 TFE

N  Param.: 10.30

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
chloride (in hexafluoroisopropanol)
Cl *
 HFIP

N  Param.: 8.00

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
bromide (in 80% aq EtOH)
Br *
 water-EtOH mix

N  Param.: 14.50

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
bromide (in 50% aq EtOH)
Br *
 water-EtOH mix

N  Param.: 13.60

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
bromide (in H2O)
Br *
 water

N  Param.: 11.70

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
bromide (in 20% aq MeCN)
Br *
 water-MeCN mix

N  Param.: 12.20

sN Param.: 0.60		 * J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n