Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
MacMillan-iminium ion (2nd generation)	MeCN	E Param.: -5.52	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
(mor)2CH+		E Param.: -5.53	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
Vilsmeier ion		E Param.: -5.77	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
4-aza-6-nitrobenzofuroxan		E Param.: -5.86	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
(mpa)2CH+		E Param.: -5.89	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(4-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium	dichloromethane	E Param.: -5.90	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(2S,5S)-5-benzyl-3-methyl-4-oxo-1-(3-phenylallylidene)-2-((E)-styryl)imidazolidin-1-ium	dichloromethane	E Param.: -5.90	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
2-phenyl-1,3-dithiolan-2-ylium ion		E Param.: -5.91	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
bis(1-methylindol-3-yl)methylium ion		E Param.: -5.99	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium	dichloromethane	E Param.: -6.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864