Carbanions

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Name	Solvent	Reactivity Parameters	Reference (title or year)
anion of malononitrile (in water)	water	N Param.: 19.50 s_N Param.: 0.55	J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e
1-(ethoxycarbonyl)-2-oxocycloheptan-1-ide	DMSO	N Param.: 19.53 s_N Param.: 0.83	Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107
1-ethoxy-2-methyl-1,3-dioxobutan-2-ide (in DMSO)	DMSO	N Param.: 19.58 s_N Param.: 0.73	Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107
enolate of 2-coumaranone (in DMSO)	DMSO	N Param.: 19.60 s_N Param.: 0.75	J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277
anion of 2-(4-NO2-C6H4)propionitrile (in DMSO)	DMSO	N Param.: 19.61 s_N Param.: 0.60	J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x
anion of ethyl cyanoacetate (in DMSO)	DMSO	N Param.: 19.62 s_N Param.: 0.67	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
anion of 4-nitrobenzyl-CN (in DMSO)	DMSO	N Param.: 19.67 s_N Param.: 0.68	J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x
anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN)	MeCN	N Param.: 19.90 s_N Param.: 0.66	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
bis(4-nitrophenyl)methanide (in DMSO)	DMSO	N Param.: 19.92 s_N Param.: 0.67	ARKIVOC 2008, (x), 37-53 10.3998/ark.5550190.[...]
2-(4-NO2-C6H4)CH(-)CO2Et (in DMSO)	DMSO	N Param.: 20.00 s_N Param.: 0.71	Eur. J. Org. Chem. 2013, , 4255-4261 10.1002/ejoc.201300265