Mayr's Database of Reactivity Parameters

Carbanions

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of nitromethane (in water)
CH2NO2- *
 water

N  Param.: 12.06

sN Param.: 0.53		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of nitromethane (in DMSO)
CH2NO2- *
 DMSO

N  Param.: 20.71

sN Param.: 0.60		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of 2-nitropropane (in DMSO)
C3H6NO2- *
 DMSO

N  Param.: 20.61

sN Param.: 0.69		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of 2-nitropropane (in water)
C3H6NO2- *
 water

N  Param.: 10.69

sN Param.: 0.56		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of phenylnitromethane (in H2O)
C7H6NO2- *
 water

N  Param.: 12.05

sN Param.: 0.53		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of phenylnitromethane (in DMSO)
C7H6NO2- *
 DMSO

N  Param.: 18.29

sN Param.: 0.71		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of p-tolylnitromethane (in water)
C8H8NO2- *
 water

N  Param.: 13.09

sN Param.: 0.50		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of p-tolylnitromethane (in DMSO)
C8H8NO2- *
 DMSO

N  Param.: 18.31

sN Param.: 0.76		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (4-nitrophenyl)nitromethane (in water)
C7H5N2O4- *
 water

N  Param.: 13.58

sN Param.: 0.52		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (4-nitrophenyl)nitromethane (in DMSO)
C7H5N2O4- *
 DMSO

N  Param.: 16.29

sN Param.: 0.75		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j