Carbanions

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Name	Solvent	Reactivity Parameters	Reference (title or year)
anion of (4-cyanophenyl)nitromethane (in DMSO)	DMSO	N Param.: 16.96 s_N Param.: 0.73	J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j
3-acetyl-2-oxotetrahydro-2H-pyran-3-ide (in DMSO)	DMSO	N Param.: 17.00 s_N Param.: 0.74	Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107
anion of 1-phenyl-2-(phenylsulfonyl)ethanone (in DMSO)	DMSO	N Param.: 17.19 s_N Param.: 0.56	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500
methoxybis(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 17.29 s_N Param.: 0.70	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)	DMSO	N Param.: 17.33 s_N Param.: 0.74	J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b
2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)	DMSO	N Param.: 17.36 s_N Param.: 0.71	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
anion of 1,3-diphenylpropane-1,3-dione (in DMSO)	DMSO	N Param.: 17.46 s_N Param.: 0.65	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500
fluorobis(phenylsulfonyl)methanide (in DMSO)	DMSO	N Param.: 17.46 s_N Param.: 0.73	Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616
1,3-dimethylbarbiturate anion (in DMSO)	DMSO	N Param.: 17.46 s_N Param.: 0.72	J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223
anion of ethyl 3-oxo-3-phenylpropanoate (in DMSO)	DMSO	N Param.: 17.52 s_N Param.: 0.74	Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500