Mayr's Database of Reactivity Parameters

Carbanions in DMSO

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions
2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 Found 117 molecules, displaying page 6 of 12 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO)
C9H8F3O2S-*
 DMSO

N  Param.: 19.35

sN Param.: 0.67		***J. Am. Chem. Soc. 2007, 129, 9753-9761
10.1021/ja072135b
anion of 4-cyanobenzyl-CN (in DMSO)
C9H5N2-*
 DMSO

N  Param.: 25.11

sN Param.: 0.54		***J. Org. Chem. 2009, 74, 75-81
10.1021/jo802241x
anion of 4-cyanobenzyl trifluoromethyl sulfone (in DMSO)
C9H5F3NO2S-*
 DMSO

N  Param.: 16.28

sN Param.: 0.75		***J. Am. Chem. Soc. 2007, 129, 9753-9761
10.1021/ja072135b
anion of 4-(trifluoromethyl)benzyl-CN (in DMSO)
C9H5F3N-*
 DMSO

N  Param.: 27.28

sN Param.: 0.50		***J. Org. Chem. 2009, 74, 75-81
10.1021/jo802241x
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)
C9H5F6O2S-*
 DMSO

N  Param.: 17.33

sN Param.: 0.74		***J. Am. Chem. Soc. 2007, 129, 9753-9761
10.1021/ja072135b
anion of 3-oxo-3-phenylpropanenitrile (in DMSO)
C9H6NO*
 DMSO

N  Param.: 16.55

sN Param.: 0.78		***Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of 3-methyl acetylacetone (in DMSO)
C6H9O2-*
 DMSO

N  Param.: 18.38

sN Param.: 0.72		***J. Am. Chem. Soc. 2003, 125, 12980-12986
10.1021/ja036838e
anion of 2-phenylmalononitrile (in DMSO)
C9H5N2*
 DMSO

N  Param.: 15.58

sN Param.: 1.00		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
anion of 2-phenyl-propionitrile (in DMSO)
C9H8N-*
 DMSO

N  Param.: 28.95

sN Param.: 0.58		***J. Org. Chem. 2009, 74, 75-81
10.1021/jo802241x
anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO)
C14H10NO2S*
 DMSO

N  Param.: 15.97

sN Param.: 0.72		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513